Product

Laboratory Instruments

Mass Spectrometer Systems

Gas Chromatograph-Mass Spectrometers (GC/MS)

GCMS-QP2010 Plus

- Shimadzu Supports Compliance with Regulations -

What is RoHS?

(RoHS: Restriction of the use of certain Hazardous Substances)

In accordance with the EU (European Union) directives on Restriction of Hazardous Substances in Electrical and Electronic Equipment (RoHS), from July of 2006, electrical products exported to Europe must not contain any of the specified hazardous metals, namely, cadmium, lead, mercury, and hexavalent chromium, or the specified hazardous substances, namely, polybrominated biphenyl (PBB) and polybrominated diphenyl ether (PBDE). The use of parts and materials free of hazardous substances, as exemplified by green procurement, has become an important issue in commercial transactions. There are corporations that have established their own criteria and demand analysis reports from suppliers of materials such as plastic and resin parts used in electrical and electronic equipment.

PBB,PBDE

 

Regulated Elements/Substances in RoHS and the Corresponding Analytical Instruments

Hazardous metal/substances
Prescribed
PoHS limits
Recommended instruments for inspection
High precision analysis
Screening
Cd, Pb, Hg Cd: 100ppm
Pb, Hg: 1,000ppm
AAS
ICP
EDX
Hexavalent
Chromium(Cr6+)
1,000ppm (For analysis of total chromium)
AAS
ICP
UV-VIS
(For selective analysis of Cr6+)
UV-VIS
(For analysis of total chromium)
EDX
Brominated
flame retardants
(PBB, PBDE)
1,000ppm GCMS (For selective analysis)
FTIR
(For analysis of total bromine)
EDX

Brominated Flame Retardants analysis by Shimadzu GCMS-QP2010 Plus

Brominated Flame Retardants analysis by Shimadzu GCMS-QP2010

The constituents of brominated flame retardants are separated with a gas chromatograph and detected with a mass spectrometer. This makes it possible to analyze brominated flame retardants with a high degree of precision. In order to ensure high accuracy, samples must be treated beforehand to remove resins or other substances that may obstruct analysis.

PBB, PBDE analysis methods

-All methods are available by Shimadzu GCMS-QP2010 Plus-

Simple method

  DI-MS : Direct injection method.
  EGA-MS : Evolved Gas Analysis method by Pyrolysis system(PY-2020iD).

Highly sensitive method

  PYR-GCMS : Thermal decomposition method by Pyrolysis system (PY-2020iD).

Highly sensitive and precise method

  Solvent extraction method

[Application Notes]

Analysis of Brominated Flame Retardantsby GC/MS (PDF 54KB)
Analysis of Brominated Flame Retardants by Evolved Gas Analysis Method

Example of Analysis Using EGA-GCMS
Total ion chromatogram of standard solution at 2mg/mL in scan mode
BDE203 (Octa-BDE)、BDE206 (Nona-BDE)、BDE206 (Deca-BDE)